Large, Tunable Liquid Crystal Pretilt Achieved by Enhanced Out-of-Plane Reorientation of Azodye Thin Films

Langmuir. 2020 Jul 28;36(29):8554-8559. doi: 10.1021/acs.langmuir.0c01371. Epub 2020 Jul 17.

Abstract

In-plane, or azimuthal, photo-reorientation of azodye films using polarized exposure makes them promising alignment layers for a host of liquid crystal (LC) applications beyond displays including beam steering, q-plates, liquid crystal elastomer origami, and control of active matter. Out-of-plane, or polar, reorientation of azodye films, which dictates the liquid crystal pretilt, has received far less attention. Spatial control over the full polar and azimuthal orientation enables the generation of complex patterns that have broad interests and applications. In this paper, we describe an enhanced out-of-plane reorientation in Brilliant Yellow films utilizing a two-step exposure and demonstrate a liquid crystal pretilt angle that is tunable over a range of 0-33° with the associated anchoring strength of the alignment layer being unaffected by the inclusion of a pretilt. We report an order of magnitude increase in both amplitude and tunability of the pretilt angle in terms of previous results for single photoalignment films. This is a significant result for liquid crystal applications because it offers a simple, scalable, single-component solution with the potential to provide three-dimensional (3-D) patternability of the LC director at the surface.