Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

Kentaro Fuku; Momoka Miyata; Shinya Takaishi; Takefumi Yoshida; Masahiro Yamashita; Norihisa Hoshino; Tomoyuki Akutagawa; Hiroyoshi Ohtsu; Masaki Kawano; Hiroaki Iguchi

doi:10.1039/d0cc03062g

Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

Chem Commun (Camb). 2020 Aug 7;56(61):8619-8622. doi: 10.1039/d0cc03062g. Epub 2020 Jul 1.

Authors

Kentaro Fuku¹, Momoka Miyata, Shinya Takaishi, Takefumi Yoshida, Masahiro Yamashita, Norihisa Hoshino, Tomoyuki Akutagawa, Hiroyoshi Ohtsu, Masaki Kawano, Hiroaki Iguchi

Affiliation

¹ Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, Japan. h-iguchi@tohoku.ac.jp.

PMID: 32609109
DOI: 10.1039/d0cc03062g

Abstract

A flexible coordination polymer with a naphthalenediimide core exhibited reversible desorption-adsorption of solvent molecules and an enhancement of electrical conductivity (∼10^-7 S cm^-1) upon chemical reduction using hydrazine.