Electrogenerated chemiluminescence of Ru(bpy)32+ at MoS2 nanosheets modified electrode and its application in the sensitive detection of dopamine

Abstract

Electrogenerated chemiluminescence (ECL) of Ru(bpy)₃²⁺ was studied at a MoS₂ nanosheets modified glassy carbon electrode (MoS₂NS/GCE) in neutral condition. Electrochemical results revealed that MoS₂ nanosheets could significantly catalyze the electrochemical oxidation of Ru(bpy)₃²⁺, as a result, strong anodic ECL was obtained. Several impact factors, such as the modified amount of MoS₂ nanosheets suspension, the pH value, and the concentration of Ru(bpy)₃²⁺, were investigated to obtain the optimal experimental condition. Dopamine exhibited apparent inhibiting effect on ECL intensity of Ru(bpy)₃²⁺-MoS₂ nanosheets through energy transfer process, and could be sensitively detected in the range of 1.0 × 10^-9 to 1.0 × 10^-4 mol L^-1. The linear equation between the decrease of ECL intensity and the logthium of dopamine concentration was determined as ΔI = 9965.02 + 1077.03lgC (C in mol L^-1), with the detection of 8.5 × 10^-10 mol L^-1 (3σ). The modified electrode exhibited satisfactory sensitivity, selectivity, and stability, which can be used to detect dopamine in real samples.

Keywords: Dopamine; Electrogenerated chemiluminescence; MoS(2) nanosheets; Ru(bpy)(3)(2+).