Interface Design of SnO2@PANI Nanotube With Enhanced Sensing Performance for Ammonia Detection at Room Temperature

Anqiang Jia; Bitao Liu; Haiyan Liu; Qiufeng Li; Yingxia Yun

doi:10.3389/fchem.2020.00383

Interface Design of SnO₂@PANI Nanotube With Enhanced Sensing Performance for Ammonia Detection at Room Temperature

Front Chem. 2020 Jun 3:8:383. doi: 10.3389/fchem.2020.00383. eCollection 2020.

Authors

Anqiang Jia^{1

2

3}, Bitao Liu², Haiyan Liu³, Qiufeng Li³, Yingxia Yun¹

Affiliations

¹ Department of Urban and Rural Planning, School of Architecture, Tianjin University, Tianjin, China.
² Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing, China.
³ Institute of Urban and Rural Construction, College of Science, College of Animal Science and Technology, Hebei Agricultural University, Baoding, China.

Abstract

Gas sensors with excellent stability and a high response at room temperature has drawn a great deal of attention and demand for them is huge. Surface designs provide inspiration toward making more useful sensor devices. The facile electrospinning process and Ar plasma treatment are used to fabricate rich and stable oxygen vacancies that contain a core-shell structured SnO₂ polyaniline (PANI) nanotube. It shows that the induced surface oxygen vacancies would accelerate the PANI shell to generate more protons, which can enhance its sensor responsibility through reacting with the target Ammonia (NH₃) gas. It was also found that the obtained oxygen vacancies can be well-protected by the coated PANI shell, which enhance and stabilize the gas response. It shows that the room temperature for the gas response of NH₃ can reach up to 35.3 at 100 ppm. Finally, its good stability is demonstrated by the response-recovery performances carried out over 3 months and multiple cycles. This work indicates that this well-designed PANI-coated plasma-treated SnO₂ is a potential way to design ammonia gas sensors.

Keywords: PANI-T-SnO2; ammonia sensor; interface design; oxygen vacancies; room temperature.