Highly efficient removal of silver nanoparticles by sponge-like hierarchically porous thiourea-formaldehyde resin from Water

Abstract

With the increasing production and rapid market penetration as well as the confirmation of the toxic effects, silver nanoparticles (AgNPs) are one kind of newly emerging environmental contaminants of high concern. It is urgent to develop the efficient method to remove them from the environment. In this study, the sponge-like hierarchically porous thiourea-formaldehyde (TF) resin rich with nitrogen and sulfur was for the first time proposed as the adsorbent to achieve this goal. With enormous interconnected layer structure and plentiful macropores, the porous TF resin provided abundant available interaction sites and fast mass transfer to adsorb citrate stabilized AgNPs (citrate-AgNPs). Fast adsorption rate and high adsorption capacity (2478 mg/g) were obtained based on the electrostatic and metal-ligand interactions. Heterogeneous aggregation and simultaneous adsorption contributed to this removal process. Furthermore, with the assistance of NaCl, the porous TF resin exhibited largely enhanced removal efficiency towards citrate-AgNPs up to 98.7 % in 5 min, possibly due to the co-operation of adsorption and coagulation. This study proposed a promising adsorbent to remove AgNPs and provided a referential strategy to design highly efficient adsorbents for removal of nanoparticles.

Keywords: Adsorption; Hierarchically porous structure; Silver nanoparticles; Sponge-like material; Thiourea-formaldehyde resin.