This study explores the contamination potential of groundwater due to the use of sodium chloride (NaCl) in the wintertime. The research was conducted in two Iranian cities, Malayer and Hamedan, where groundwater is the major source of water for drinking and irrigating purposes. However, the amount of deicing salt used in the former is about 10 times less than that used in the latter. The assessment of geochemical dataset from 2004 to 2018 revealed no significant trend in the groundwater characteristics of Malayer where the water quality indices were in the range of WHO and USEPA permissible limits. In contrast, the indices had a continually increasing trend (~ 2.3% annually) in Hamedan's supply wells over the same period and particularly near the urban areas that showed higher levels (> 5 times on average) than those observed in Malayer. This could mainly be ascribed to the influx of halite. Based on the USSL diagram, the water samples retrieved from the latter system were mostly classified as C3-S1 (decreasing the soil fertility) and even as C4-S2 (harmful for agriculture activities). Chloride contamination rates also reached 250 mg/L, which could negatively affect the water potability and threaten the aquatics microorganisms. In this region, a rather similar distribution of NaCl and arsenic was observed, implying mobilization of toxic trace metals with the increased salt encroachment into the aquifer. Based on such findings, it is suggested that in snow-influenced cities (e.g., Hamedan), new approaches for winter maintenance be considered to prevent the gradual deterioration of water resources.
Keywords: Deicing salt; Ecological risks; Groundwater contamination; Urban environments.