Effects of hydrothermal pretreatment on the mono- and co-digestion of waste activated sludge and wheat straw

Abstract

The refractory properties of waste activated sludge and wheat straw inhibit their bioenergy recovery by anaerobic digestion. This paper attempted to estimate the digestive performance, energy conversion efficiency and economic feasibility of wheat straw mono-digestion and its co-digestion with sludge by hydrothermal pretreatment at different temperature gradients (125, 150 and 175 °C). The results illustrated that the hydrolysis of both wheat straw and sludge were improved with the temperature increasing. It is noted that after pretreatment at 175 °C, wheat straw mono-digestion obtained the cumulative specific methane yield of 168.8 mL/g·VS, 6.9% reduction compared to the unpretreated straw (181.4 mL/g·VS) due to the inhibition by by-products (furfural and 5-hydroxymethylfurfural, 5-HMF) formed at high temperatures. The highest cumulative specific methane yield of 225.7 mL/g·VS was achieved by the co-digestion of pretreated wheat straw and pretreated sludge under 175 °C, indicating that the participation of sludge in co-digestion improved the buffer capacity of the system to relieve the inhibition. In addition, the co-digestion of sludge and wheat straw both pretreated at 175 °C obtained the maximum energy production of 7901.1 MJ/t, 52% promotion compared to the mono-digestion without pretreatment. The results of economic analysis showed that the mono-digestion of wheat straw obtained relatively low net profits and the mono-digestion of sludge pretreated at 175 °C achieved the highest net profit of 31.44 US$/t. These results suggest that the co-digestion of both pretreated wheat straw and sludge can achieve the highest biogas production and energy conversion efficiency.

Keywords: Anaerobic digestion; Economic analysis; Energy conversion; Hydrothermal pretreatment; Waste activated sludge; Wheat straw.