Bulk and surface structural changes in high nickel cathodes subjected to fast charging conditions

Chem Commun (Camb). 2020 Jun 25;56(51):6973-6976. doi: 10.1039/d0cc02579h.

Abstract

A layered oxide cathode, LiNi0.6Mn0.2Co0.2O2, undergoes noticeable crystal expansion by losing significantly higher amounts of Li+ at the end of fast charging cycles. However, the bulk structure of the cycled NMC622 is restored back to its pristine discharged state when intercalated with enough lithium ions during an electrochemical process.