A 2-to-2' 18-to-18' doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad

Chem Commun (Camb). 2020 Jun 25;56(50):6846-6849. doi: 10.1039/d0cc02543g. Epub 2020 May 20.

Abstract

The synthesis and properties of a 2-to-2' 18-to-18' doubly linked Ni(ii) norcorrole dimer are described. It adopts a highly planar structure, resulting in effective electronic interactions between the constituent norcorrole units. Nevertheless, each norcorrole unit exhibits substantial antiaromaticity, which stands in sharp contrast to stacked norcorrole dimers.