Theoretical analysis and a large number of experiments have proved that plasma components do not satisfy Boltzmann-Gibbs statistics and can be well described by nonextensive statistical mechanics, while new plasma parameters, electron nonextensive parameters, which are introduced to describe the nonextensive properties of plasma, cannot be diagnosed yet. Here we show measurement of electron nonextensive parameters of plasma with a nonextensive single electric probe. Our results show that nonextensive electric probe may play a role in plasma diagnosis, measuring nonextensivity of plasma and improving diagnostic accuracy of other plasma parameters. We expect the proposed nonextensive single electric probe can be starting point of more complex nonextensive electric probe. In addition, nonextensive electric probe is an important means to study various plasma waves and instability, turbulence, and anomalous transport, and a definite and quantitative test of the theory of nonextensive geodetic acoustic models will be relevant to such development.