We numerically study the spatiotemporal dynamics and predictability of a buoyancy-driven turbulent fire. A significant transition from order to disorder structures can be observed from the mean degree in the spatial horizontal visibility graph. The gravitational term (baroclinic torque term) in the vorticity equation has a significant impact on the formation of the order (disorder) structure in the near field (far field). The entropy flow transport from temperature to flow velocity fluctuations is predominant near the interface between hot combustion products and ambient air. The transfer entropy is an important measure for determining the predictability of flow velocity fluctuations in the near field obtained by reservoir computing.