In this article, we describe the acquisition of depth profiles, in particular of paint layers, in the static gradient of a high field magnet, providing a superior sensitivity. The main objective are reference profiles that help to understand scans made with noninvasive unilateral nuclear magnetic resonance (NMR), which often suffers from poor signal-to-noise ratio when working with real samples. Various technical aspects like the coil geometry and the limit of resolution are investigated. A major advancement is the use of frequency-modulated pulses that are very broadband and at the same time very short (25 μs). The latter is necessary to allow the acquisition of a CPMG echo train of old, rigid paint material. Despite being far from adiabatic, they provide uniform excitation and refocusing over 1 MHz, which corresponds to about 400 μm with the used gradient. We show that the uniformity is even sufficient to obtain biexponential relaxation profiles. With these tools, a paint sample from a restoration campaign is analyzed with different contrast criteria: The original and two layers from former restoration attempts can be visualized, and furthermore, the relaxation profiles allow to study the migration of plasticizing molecules.
Keywords: 1H; NMR; depth profiles; frequency-modulated pulses; paint.
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