(Thio)urea cocatalyst accelerates O-monoacyltartaric acid (MAT)-catalyzed enantioselective conjugate addition of boronic acid to unsaturated ketone. Kinetic studies of this reaction revealed first-order dependence of each substrate and catalyst and second-order dependence of (thio)urea, leading to reduction of the catalyst loading and development of more active and enantioselective MAT monoaryl ester catalyst.