Ion chromatography (IC) is a variant of high-performance liquid chromatography. Its most important applications include the determination of inorganic and some organic ions in different types of liquid samples. The development of new types of stationary phases with various separation mechanisms, sample preparation methods, and detection modes has extended ion chromatography applications to practically all ionic and ionogenic substances, as well as extending sample types to include gaseous and solid matrices. Carboxylic acids and their derivatives are examples of compounds that are becoming more frequently analyzed using ion chromatography and related techniques. Their occurrence in the environment can be natural or anthropogenic in origin and are broadly used in various industries and daily life. This article discusses the applications of ion chromatography and related techniques for the determination of carboxylic acids in different types of liquid, solid, and gaseous matrices. It also presents detailed methodologies and literature data on this subject from the last 15 years.
Keywords: Carboxylic acids; environment; ion chromatography; ion pair chromatography; ion-exclusion chromatography.