A method for designing a novel class of gold-containing molecules

Chem Commun (Camb). 2020 May 18;56(40):5433-5436. doi: 10.1039/d0cc01227k. Epub 2020 Apr 14.

Abstract

We propose a novel class of gold-containing molecules, which have been designed using conjugated carbon structures as templates. The sp-hybridized carbons of C2 moieties are replaced with a gold atom and one of the adjacent carbons is replaced by nitrogen. Applying the procedure to hexadehydro[12]annulene yields the well-known cyclic trinuclear gold(i) carbeniate complex. Planar, tubular and cage-shaped complexes can be obtained by taking similar sp-hybridized carbon structures as the starting point.