To increase the performance efficiency and decrease the costs for organic dye wastewater purification, two fibrous adsorbents based on polymeric salicyl active esters were developed by means of a simple two-step approach. For the first time, salicyl-based active ester polymers were electrospun into fibrous membranes and subsequently postmodified with the desired functional groups under simple and mild reaction conditions. The morphology of the produced fibrous adsorbents was characterized by scanning electron microscopy (SEM), the surface properties were analyzed by nitrogen adsorption/desorption isotherms and contact angle measurements, and the completeness of the postmodification process was determined by Fourier transform infrared (FTIR) and elemental analyses. The adsorbents were further tested for their adsorption and selectivity performance of different organic dyes as well as for their recyclability. To explore the adsorption mechanism, four kinetic models and three isotherm models were used to analyze the adsorption data. The results indicated that the fibrous adsorbents showed an extremely high adsorption capacity for the anionic dye methyl blue. The fibrous adsorbents were also able to selectively adsorb anionic dyes from a mixture of anionic and cationic dyes, and they could be recycled at least 10 times. The simple and cost-efficient development process of these fibrous adsorbents and their excellent performance make them promising materials for further research and application in the area of water treatment.
Keywords: electrospinning; fibers; organic dyes; polymeric active esters; postmodification; selective adsorption; water purification.