Sustainable and Efficient Route for the Regeneration of Carbonyl Compounds from Oximes Using Aqueous Extract of Sapindus laurifolia under Microwave Radiation

Debadutta Das; Ranjan K Mohapatra; Pankaj K Parhi; Ashish K Sarangi; Raghaba Sahu; Soumya R Barik

doi:10.1021/acsomega.0c00774

Sustainable and Efficient Route for the Regeneration of Carbonyl Compounds from Oximes Using Aqueous Extract of Sapindus laurifolia under Microwave Radiation

ACS Omega. 2020 Mar 25;5(13):7716-7721. doi: 10.1021/acsomega.0c00774. eCollection 2020 Apr 7.

Authors

Debadutta Das¹, Ranjan K Mohapatra², Pankaj K Parhi^{3

4}, Ashish K Sarangi⁵, Raghaba Sahu⁶, Soumya R Barik⁷

Affiliations

¹ Department of Chemistry, Sukanti Degree College, Subarnapur, Odisha 767017, India.
² Department of Chemistry, Government College of Engineering, Keonjhar, Odisha 758002, India.
³ School of Chemical Technology, KIIT Deemed to be University, Bhubaneswar, Odisha 751024, India.
⁴ Convergence Research Center for Development of Mineral Resources (DMR), Korea Institute of Geosciences and Mineral Resources (KIGAM), Daejeon 305-350, South Korea.
⁵ Department of Chemistry, School of Applied Sciences, Centurion University of Technology and Management, Odisha 767001, India.
⁶ College of Pharmacy, Seoul National University, Seoul 08826, South Korea.
⁷ Department of Chemistry, C. V. Raman College of Engineering, Bhubaneswar, Odisha 752054, India.

Abstract

The synthesis of organic compounds using aqueous medium has become an indispensable tool for modern chemical synthesis strategies because of its ability to produce pure products with higher yield at ambient temperature. The conversion of oxime group into carbonyl group serves as a key step for several organic syntheses. This article describes the regeneration of carbonyl compounds from the oxime group present in various carbon skeletons using I₂ and aqueous extract of Sapindus laurifolia under microwave radiation. A correlation has been established between the critical micellar concentration of saponin extracted from Sapindous laurifolia and the yield percentage of regenerated different carbonyl compounds. An effortless, competent, and environmentally compassionate protocol for the regeneration of carbonyl compound with a high percent of yield in the range 45-95% could be achieved.