Studies were made on the influence of temperature and oxygen to carbon ratio (the O/C ratio) on the properties of particles during water coal slurry gasification by taking a new-type coal-water slurry gasifier as the thermal experiment platform, coal-water slurry as a gasification material, and oxygen as the oxidant. The results show that the higher the gasification temperature, the more spherical particles are generated, the higher the content of Na, Fe, and S on the particle surface, and the greater the mass percentage of fine particles. With increase in the O/C ratio, the production of fine particles also increases, while the carbon content of the particles decreases. When the O/C ratio is 1.1, fine particles mainly exist in the form of aggregates; the O/C ratio has little influence on the contents of the particle surface, such as Na, Al, Si, Fe, and S. The effect of the O/C ratio on particle size distribution is most obvious when the ratio is 1: the fine particles are the most prevalent and the coarse particles are the fewest. When the ratio is 1.1, the amount of coarse particles is the largest and the amount of fine particle aggregates is also greater. When the ratio is 0.9, the particle size distribution is intermediate to the two cases.
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