Organic supercapacitors have attracted interest as promising "green" and efficient components in energy storage applications. A polydiacetylene derivative coupled with reduced graphene oxide was employed, for the first time, to generate an organic pseudocapacitance-based supercapacitor that exhibited excellent electrochemical properties. Specifically, diacetylene monomers were functionalized with perylenediimide (PDI), spontaneously forming elongated microfibers. Following polymerization through UV irradiation, the PDI-polydiacetylene microfibers were interspersed with reduced graphene oxide (rGO), generating a porous electrode material exhibiting a high surface area and facilitating efficient ion diffusion, both essential preconditions for supercapacitor applications. We show that PDI-polydiacetylene has an important role in enhancing the electrochemical properties as a supercapacitor electrode. Besides stabilizing the microporous electrode organization, the delocalized π electrons in both the PDI residues and conjugated network of the polydiacetylene contributed to a significantly higher capacitance (specific capacitance >600 F g-1 at 1 A g-1 current density), longer discharge time, and high power density. The PDI-polydiacetylene-rGO electrodes were employed in a functional supercapacitor device.
Keywords: electrochemistry; organic; perylene diimide; polydiacetylene; supercapacitor.
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