Recent progresses in analytical GC and LC mass spectrometric based-methods for the detection of emerging chlorinated and brominated contaminants and their transformation products in aquatic environment

Abstract

This paper is an overview of screening methods recently developed for emerging halogenated contaminants and their transformation products. The target screening methods are available only for a limited number of emerging pollutants since the reference standards for these compounds are not always available, but a risk assessment of those micropollutants in environment must be performed anyhow. Therefore, the chromatographic techniques hyphenated with high resolution mass spectrometry (HRMS) trend to become indispensable methods for suspect and non-target screening of emerging halogenated contaminants. HRMS is also an effective tool for tentatively identification of the micropollutants' transformation products existing in much lower concentrations. To assess the transformation pathway of halogenated contaminants in environment, the non-target screening methods must be combined with biodegradation lab experiments and also with advanced oxidation and reduction processes that can mimic the transformation on these contaminants in environment. It is expected that in the future, the accurate-mass full-spectra of transformation products recorded by HRMS will be the basic information needed to elucidate the transformation pathways of emerging halogenated contaminants in aquatic environment.

Keywords: HRMS; Metabolites; Non-target screening; Suspect screening.