Unprecedented tin iodide perovskite-like structures featuring ordering of organic moieties

Jason A McNulty; Philip Lightfoot

doi:10.1039/d0cc00549e

Unprecedented tin iodide perovskite-like structures featuring ordering of organic moieties

Chem Commun (Camb). 2020 Apr 28;56(33):4543-4546. doi: 10.1039/d0cc00549e. Epub 2020 Mar 23.

Authors

Jason A McNulty¹, Philip Lightfoot

Affiliation

¹ School of Chemistry and EaStChem, University of St Andrews, St Andrews, Fife KY16 9ST, UK. pl@st-andrews.ac.uk.

PMID: 32202274
DOI: 10.1039/d0cc00549e

Abstract

Two unique hybrid tin iodides, with generic compositions A_0.5A'_0.5SnI₃ and A_1.5A'_0.5SnI₄ have been prepared. Each shows ordering of the two organic moieties (A and A') on distinct crystallographic sites, leading to novel 3D and 2D structure types, respectively.