Nanographenes are a popular area of research due to their promising properties for electronics. Over the last twenty years there has been a significant increase in interest in the development of contorted nanographenes. While many top-down techniques are employed in the synthesis of these planar nanographenes, the use of alkynes in bottom-up syntheses allows for easy functionalization and the development of contorted nanographenes. The syntheses of contorted nanographenes with a focus on utilizing alkynes is reviewed here.