Response surface methodology based on central composite design for simultaneous adsorption of rare earth elements using nanoporous calcium alginate/carboxymethyl chitosan microbiocomposite powder containing Ni0.2Zn0.2Fe2.6O4 magnetic nanoparticles: Batch and column studies

Abstract

In this research paper, the utilization of the magnetic calcium alginate/carboxymethyl chitosan/Ni_0.2Zn_0.2Fe_2.6O₄ (CA/CMC/Ni_0.2Zn_0.2Fe_2.6O₄) was investigated for the simultaneous aqueous adsorption of Nd (III), Tb (III), and Dy (III). The magnetic products were characterized by FE-SEM, EDX, XRD, FT-IR, TGA, and VSM techniques. The saturation magnetization value for Ni_0.2Zn_0.2Fe_2.6O₄ and CA/CMC/Ni_0.2Zn_0.2Fe_2.6O₄ was found to be 45.87 and 14.14 emu/g, respectively. Using RSM, a quadratic polynomial equation was obtained to predict the adsorption efficiency of each ion. Under the conditions of pH = 5.5, adsorbent dosage of 0.1 g, initial concentration of 30 mg/L, and contact time of 53 min predicted by RSM, the adsorption efficiencies of Nd (III), Tb (III), and Dy (III) were respectively 95.72, 96.17, and 99.44%. The isotherm and kinetic data were respectively fitted well with Freundlich and pseudo-second-order (PSO) models. The desorption of the loaded ions was effectively carried out by 0.2 M HNO₃, and the adsorbent was consecutively utilized with 2.54, 1.63, and 1.16% decrease in adsorption efficiency for Nd (III), Tb (III), and Dy (III), respectively, after the forth cycle. Additionally, the adsorption behavior of the CA/CMC/Ni_0.2Zn_0.2Fe_2.6O₄ towards Nd (III), Tb (III), and Dy (III) was studied by using a fixed-bed column technique.

Keywords: Adsorption; Calcium alginate; Carboxymethyl chitosan; Ni(0.2)Zn(0.2)Fe(2.6)O(4); RSM; Rare earth elements.