Factors affecting co-valorization of fayalitic and ferronickel slags for the production of alkali activated materials

Konstantinos Komnitsas; Lourdes Yurramendi; Georgios Bartzas; Vasiliki Karmali; Evangelos Petrakis

doi:10.1016/j.scitotenv.2020.137753

Factors affecting co-valorization of fayalitic and ferronickel slags for the production of alkali activated materials

Sci Total Environ. 2020 Jun 15:721:137753. doi: 10.1016/j.scitotenv.2020.137753. Epub 2020 Mar 5.

Authors

Konstantinos Komnitsas¹, Lourdes Yurramendi², Georgios Bartzas³, Vasiliki Karmali⁴, Evangelos Petrakis⁴

Affiliations

¹ Technical University of Crete, School of Mineral Resources Engineering, University Campus, Kounoupidiana, 73100 Chania, Greece. Electronic address: komni@mred.tuc.gr.
² Tecnalia, Energy and Environment Division, Mikeletegi Pasealekua 2, E-20009 San Sebastián, Spain.
³ National Technical University of Athens, School of Mining and Metallurgical Engineering, 9 Heroon Polytechniou str., 157 80 Zografos, Athens, Greece.
⁴ Technical University of Crete, School of Mineral Resources Engineering, University Campus, Kounoupidiana, 73100 Chania, Greece.

PMID: 32171143
DOI: 10.1016/j.scitotenv.2020.137753

Abstract

The first objective of this experimental study is the assessment of the alkali activation potential of two types of fayalitic slags, an as-received one (FS) and the one obtained after plasma treatment (FSP) of the initial FS, for the production of alkali activated materials (AAMs). Furthermore, the second objective is the elucidation of the co-valorization potential of FS and FSP slags when mixed with ferronickel (FeNi) slag (LS). The alkaline activating solution used was a mixture of sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃). The effect of various operating parameters, such as H₂O/Na₂O and SiO₂/Na₂O ratios present in the activating solution, curing temperature, curing period and ageing period on the compressive strength, density, water adsorption, porosity and toxicity of the produced AAMs was explored. The structural integrity of selected AAMs was investigated after firing specimens for 6 h at temperature up to 500 °C, immersion in distilled water and acidic solution or subjection to freeze-thaw cycles for a period of 7 or 30 days. The results of this study show that FS- and FSP-based AAMs acquire compressive strength of 44.8 MPa and 27.2 MPa, respectively. When FS and FSP were mixed with LS at 50:50%wt ratios the compressive strength of the produced specimens increased to 64.3 MPa and 45.8 MPa, respectively. Furthermore, selected AAMs produced after co-valorisation of slags retained sufficient compressive strength after firing at 500 °C, 45-68 MPa, and exhibited very low toxicity. These findings prove the alkali activation potential of fayalitic slags as well as their co-valorization with ferronickel slag for the production of AAMs, an approach which is in line with the principles of zero-waste and circular economy.

Keywords: Alkali activated materials (AMMs); Alkali activation; Metallurgical slags; Properties; Reactivity of slags.