Alumina-functionalized ordered mesoporous silica SBA-15 particles have been proposed to stabilize Pickering emulsions. Functionalization of SBA-15 particles have been performed by depositing alumina using a two-step synthesis (first, silica condensation, followed by alumina precipitation). Three different Al to Si ratios have been prepared. The calcined materials have been characterized by TEM, SEM, XRD, N2 physisorption, and zeta potential, in order to determine key physicochemical properties, and the alumina localization. The emulsifying and stabilizing properties of the calcined particles have been evaluated for water/toluene-based Pickering emulsions.