Abstract
We present a simple strategy for the synthesis of main chain oligonucleotide rotaxanes with precise control over the position of the macrocycle. The novel DNA-based rotaxanes were analyzed to assess the effect of the mechanical bond on their properties.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkynes / chemical synthesis
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Alkynes / chemistry
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Azides / chemical synthesis
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Azides / chemistry
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Click Chemistry
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Copper / chemistry*
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Cycloaddition Reaction
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DNA / chemical synthesis*
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DNA / chemistry
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Macrocyclic Compounds / chemical synthesis
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Macrocyclic Compounds / chemistry
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Oligonucleotides / chemical synthesis*
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Oligonucleotides / chemistry
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Rotaxanes / chemical synthesis*
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Rotaxanes / chemistry
Substances
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Alkynes
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Azides
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Macrocyclic Compounds
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Oligonucleotides
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Rotaxanes
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Copper
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DNA