A review of carbon quantum dots and their applications in wastewater treatment

Umairah Abd Rani; Law Yong Ng; Ching Yin Ng; Ebrahim Mahmoudi

doi:10.1016/j.cis.2020.102124

A review of carbon quantum dots and their applications in wastewater treatment

Adv Colloid Interface Sci. 2020 Apr:278:102124. doi: 10.1016/j.cis.2020.102124. Epub 2020 Feb 19.

Authors

Umairah Abd Rani¹, Law Yong Ng², Ching Yin Ng³, Ebrahim Mahmoudi⁴

Affiliations

¹ Department of Chemical Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Jalan Sungai Long, Bandar Sungai Long, 43000 Kajang, Selangor, Malaysia.
² Department of Chemical Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Jalan Sungai Long, Bandar Sungai Long, 43000 Kajang, Selangor, Malaysia. Electronic address: lyng@utar.edu.my.
³ Department of Chemical Engineering, Faculty of Engineering, Technology and Built Environment, UCSI University (Kuala Lumpur Campus), No. 1, Jalan Menara Gading, UCSI Heights (Taman Connaught), 56000 Cheras, Kuala Lumpur, Malaysia.
⁴ Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia.

PMID: 32142942
DOI: 10.1016/j.cis.2020.102124

Abstract

Carbon quantum dots (CQDs) are a fascinating class of carbon nanoparticles with sizes around 10 nm. The unique properties of CQDs are low toxicity, chemical inertness, excellent biocompatibility, photo-induced electron transfer and highly tunable photoluminescence behaviour. Sustainable raw materials are commonly used for the fabrication of CQDs because they are cost-effective, eco-friendly and effective to minimise waste production. CQDs can be fabricated using laser ablation, microwave irradiation, hydrothermal reaction, electrochemical oxidation, reflux method and ultrasonication. These methods undergo several chemical reactions such as oxidation, carbonisation, pyrolysis and polymerisation processes to produce CQDs. Due to small particle sizes of CQDs, they possess strong tunable fluorescent properties and highly photo-luminescent emissions. It also contains oxygen-based functional groups and highly desired properties as semiconductor nanoparticles. Therefore, CQDs are promising nanomaterials for photo-catalysis, ions sensing, biological imaging, heavy metal detection, adsorption treatment, supercapacitor, membrane fabrication and water pollution treatment. This review paper will discuss the physical and chemical properties of CQDs, raw materials and methods used in the fabrication of CQDs, the stability of CQDs as well as their potential applications in wastewater treatment and biomedical field.

Keywords: Carbon quantum dot; fluorescent probe; organic pollutant; photo-catalyst; wastewater treatment.

Publication types

Review