Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

Man-Bo Li; Ying Yang; Abdolrahim A Rafi; Michael Oschmann; Erik Svensson Grape; A Ken Inge; Armando Córdova; Jan-E Bäckvall

doi:10.1002/anie.202001809

Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

Angew Chem Int Ed Engl. 2020 Jun 22;59(26):10391-10395. doi: 10.1002/anie.202001809. Epub 2020 Apr 7.

Authors

Man-Bo Li^{1

2}, Ying Yang¹, Abdolrahim A Rafi³, Michael Oschmann², Erik Svensson Grape⁴, A Ken Inge⁴, Armando Córdova³, Jan-E Bäckvall^{2

3}

Affiliations

¹ Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601, P. R. China.
² Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
³ Department of Natural Sciences, Mid Sweden University, Holmgatan 10, 85179, Sundsvall, Sweden.
⁴ Department of Materials and Enviromental Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.

Abstract

A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd^II , which results in high efficiency of the heterogeneous catalytic system.

Keywords: carbonylation; heterogeneous catalysis; palladium; polycyclic compound; silver.

Grants and funding

2019-04042/Vetenskapsrådet