Novel sodium alginate-assisted MXene nanosheets for ultrahigh rejection of multiple cations and dyes

Wenjihao Hu; Lei Xie; Hongbo Zeng

doi:10.1016/j.jcis.2020.02.028

Novel sodium alginate-assisted MXene nanosheets for ultrahigh rejection of multiple cations and dyes

J Colloid Interface Sci. 2020 May 15:568:36-45. doi: 10.1016/j.jcis.2020.02.028. Epub 2020 Feb 10.

Authors

Wenjihao Hu¹, Lei Xie¹, Hongbo Zeng²

Affiliations

¹ Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 1H9, Canada.
² Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 1H9, Canada. Electronic address: hongbo.zeng@ualberta.ca.

PMID: 32086010
DOI: 10.1016/j.jcis.2020.02.028

Abstract

Energy-efficient process for water desalination and organic dye separation is urgently needed to meet the dramatically increasing demand for fresh water globally. Nb₂CT_x MXene, as one type of 2D transition metal carbides (TMDCs) family, has attracted tremendous research interest in the fields of separation technology over the past decade. However, it has been challenging to fabricate surface-modified Nb₂CT_x MXene nanosheet films with superior performance for desalination and separation applications. Herein, we report a novel, facile and scalable sodium alginate (SA)-assisted surface termination method to fabricate SA-modified Nb₂CT_x MXene (NbSA) nanosheets. It is found that films of the NbSA nanosheets demonstrate overall better performance than bare Nb₂CT_x MXene nanosheet film. The NbSA film with a thickness of 5 µm shows >95% rejection towards various cations under forward osmosis process. The film also shows a fast water flux of 2200 ± 100 L m^-2 h^-1 bar^-1 (LMHB) with almost 100% rejection rate towards multiple dyes under vacuum-driven filtration mode. Moreover, the NbSA film has exhibited selective separation performance on Li⁺/Mg²⁺ mixture solution under forward osmosis process. This work reports a novel NbSA film with excellent performances for desalination and separation, with useful implications for developing 2D material films in separation processes and environmental engineering.

Keywords: 2D materials; MXene nanosheets; Organic dye separation; Rejection rate of cations; Water flux.