Optical screening for presence of banned Sudan III and Sudan IV dyes in edible palm oils

Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2020 Jul;37(7):1049-1060. doi: 10.1080/19440049.2020.1726500. Epub 2020 Feb 20.

Abstract

Due to the proven carcinogenicity of Sudan III and IV dyes, they are considered global public health issues. They are banned in all forms as food colourants. We propose the monitoring of simple and easy-to-measure optical properties of palm oils, such as the refractive indices and spectrophotometric properties, as efficient indicators to detect adulteration. Coupling these results with principal component analysis, excess refractive index, and integration of transmittance introduces a novel detection tool for the authentication of edible palm oil. This opens a new opportunity for accurate handheld devices to detect adulteration and provide control in the field. This work assessed in total of 49 samples, some collected from different parts of Ghana and others, in-house adulterated samples. The Ghana Food and Drugs Authority, who performed a complex and expensive chemical analysis of the samples, confirmed our results with good agreement.

Keywords: Edible oil; VIS/NIR spectrophotometry; excess refractive index; palm oil adulteration; principal component analysis; refractive index.

MeSH terms

  • Azo Compounds / analysis*
  • Carcinogens / analysis*
  • Food Analysis
  • Food Coloring Agents / analysis*
  • Optical Phenomena
  • Palm Oil / chemistry*

Substances

  • Azo Compounds
  • Carcinogens
  • Food Coloring Agents
  • Palm Oil
  • Scarlet Red
  • sudan III