The sequestration of Cr(VI) by zero valent iron under a non-uniform magnetic field: An interfacial dynamic reaction

Abstract

A non-uniform magnetic field was applied to sequester Cr(VI) with microscale zero-valent iron (ZVI). When the non-uniform magnetic field was applied, the average removal rate of Cr(VI) was increased and the lag phase was shortened with the increasing of magnetic field intensity. The instantaneous rate was fast at the beginning and about 40% of the Cr(VI) was sequestered rapidly when ZVI was added into the magnetic field system. Later, the sequestration rate of Cr(VI) was reduced and remained stable with time until Cr(VI) was removed completely. The instantaneous removal rate was positively correlated with ZVI dosage and the rate per unit mass of ZVI was 0.455 mg/(L·min·gZVI). The constant rate stage was not affected by the initial and the residual concentration of Cr(VI). In the case where no magnetic field was applied, the removal of Cr(VI) is a process in which ZVI is depassivated and its reactivity is restored continuously. The promotion of a magnetic field on the removal of Cr(VI) is mainly due to increasing the role of adsorbed reducing species of Fe²⁺ or Fe⁰ on the ZVI surface. Aging of ZVI under a magnetic field could enhance the release rate of Fe²⁺ in the initial 5 min though the remanence of this kind of ZVI had little effect on the enhancement of the sequestration of Cr(VI).

Keywords: Cr(VI); Interfacial reaction; Non-uniform magnetic field; Sequestration; Zero-valent iron.