Synthesis of highly fluorescent and water soluble graphene quantum dots for detection of heavy metal ions in aqueous media

Abstract

Fluorescent graphene quantum dots (GQDs) are nanomaterials which possess unique properties that show great potential in different applications. In this work, GQDs were synthesized using graphene oxide (GO) as precursor via thermal treatment at high temperature. The obtained GQDs were highly fluorescent and were suitable for the determination of heavy metal ions. X-ray diffraction, FTIR spectroscopy, and UV visible spectroscopy confirm the formation of GQDs. TEM images show that formed GQDs have size ranging from 2 to 10 nm. Emission profile of aqueous GQDs was taken by exciting GQDs at different wavelength. The intensity of GQDs remains the same for 4-5 months. Furthermore, as prepared, GQDs were used for selective recognition of Fe³⁺, Pb⁺², and Cr³⁺ from the bunch of different metal ions in aqueous media. Lower limit of detection obtained for Fe³⁺, Cr³⁺ and Pb²⁺ using GQDs were 50, 100 and 100 nM, respectively, which indicates that the GQDs can be utilized as a promising material for sensing of the heavy metal ions. Graphical abstract.

Keywords: Fluorescence; GQDs; Iron; Lead and chromium ions.