A pre-synthetic strategy to construct single ion conductive covalent organic frameworks

Juan Li; Fu-Qiang Zhang; Falian Li; Zhenzhen Wu; Canliang Ma; Qinchao Xu; Pengfei Wang; Xian-Ming Zhang

doi:10.1039/d0cc00454e

A pre-synthetic strategy to construct single ion conductive covalent organic frameworks

Chem Commun (Camb). 2020 Mar 3;56(18):2747-2750. doi: 10.1039/d0cc00454e.

Authors

Juan Li¹, Fu-Qiang Zhang², Falian Li¹, Zhenzhen Wu¹, Canliang Ma³, Qinchao Xu⁴, Pengfei Wang⁴, Xian-Ming Zhang⁵

Affiliations

¹ Institute of Crystalline Materials, Shanxi University, Wucheng Rd, No. 92, Taiyuan 030006, China. lj0511@sxu.edu.cn xmzhang@sxu.edu.cn.
² Key Laboratory of Magnetic Molecules & Magnetic Information Materials (Ministry of Education), Shanxi Normal University, Linfen, 041004, China.
³ Institute of Crystalline Materials, Shanxi University, Wucheng Rd, No. 92, Taiyuan 030006, China. lj0511@sxu.edu.cn xmzhang@sxu.edu.cn and Institute of Molecular Science, Shanxi University, 030006, Taiyuan, China.
⁴ Institute of Coal Chemistry, Chinese Academy of Sciences, 030001 Taiyuan, China.
⁵ Institute of Crystalline Materials, Shanxi University, Wucheng Rd, No. 92, Taiyuan 030006, China. lj0511@sxu.edu.cn xmzhang@sxu.edu.cn and Key Laboratory of Magnetic Molecules & Magnetic Information Materials (Ministry of Education), Shanxi Normal University, Linfen, 041004, China and Institute of Chemistry and Culture, School of Chemistry & Material Science, Shanxi Normal University, Linfen 041004, China.

PMID: 32022085
DOI: 10.1039/d0cc00454e

Abstract

A pre-synthetic strategy was developed for the construction of single ion conductive covalent organic frameworks (COFs). A high Li+ conductivity of 1.6 × 10-3 S cm-1 at 273 K was achieved, and single Na+ and K+ COFs were also obtained by using Na+ and K+ salts as monomers according to this synthetic method.