Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

Chem Commun (Camb). 2020 Feb 28;56(17):2646-2649. doi: 10.1039/c9cc08468a. Epub 2020 Feb 5.

Abstract

Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.