Distribution and health risk assessment of potentially toxic elements in soils around coal industrial areas: A global meta-analysis

Abstract

Coal production and utilization are recognized as two principal sources of potentially toxic elements in the environment. Here the published literature (2008-2018) was searched to collect data on As, Ni, Cd, Cu, Cr, Hg, Pb and Zn concentrations in soils near different types of coal industrial areas such as coal mines, thermal power plants, coal chemical plants, coal mining cities and coal waster piles. The contamination levels of soils and associated health risks were assessed using global reference materials and multiple contamination indices. The results revealed that average concentrations of potentially toxic elements varied widely, yet most of them exceeded global averages in background soils and upper continental crust concentrations. Spatial distribution analysis suggested the concentrations of potentially toxic elements varied according to coalification and combustion conditions. Higher concentrations were found in Southeast Asia, South Europe, and North Africa compared with other regions. Assessment of the geoaccumulation index revealed that contamination levels of Cd and Hg were higher than those of other elements. In particular, Ni, Cd, Zn, and Hg were most likely to accumulate in soils near coal mining areas, while Cd and Hg tended to accumulate near coal chemical plants. Regarding non-carcinogenic risks, oral ingestion was the major pathway of exposure to potentially toxic elements in coal industry-associated soils, followed by dermal contact and inhalation. Tolerable non-carcinogenic risk of potentially toxic elements and relatively high carcinogenic risks of As were observed. Children were most vulnerable to non-carcinogenic risks, while the carcinogenic risks estimated for adult and children populations were similar. Accordingly, As should be designated as top candidates for priority control to protect human health in the vicinity of coal industry-associated areas. This study provides timely information for developing control and management strategies to reduce soil contamination by potentially toxic elements in different types of coal industrial areas.

Keywords: Coal industrial area; Geoaccumulation index; Health risk; Potentially toxic elements; Soil contamination.