A high cost-performance carbon dioxide sorbent based on hierarchical porous carbons (HPCs) was easily prepared by carbonization of raw sugar using commercially available nano-CaCO3 as a double-acting template. The effects of the initial composition and carbonization temperature on the micro-mesoporous structure and adsorption performance were examined. Also, the importance of post-activation behavior in the development of micropores and synthesis route for the formation of the interconnected micro-mesoporous structure were investigated. The results revealed excellent carbon dioxide uptake reaching up 2.84 mmol/g (25oC, 1 bar), with micropore surface area of 786 m2/g, micropore volume of 0.320 cm3/g and mesopore volume of 0.233 cm3/g. We found that high carbon dioxide uptake was ascribed to the developed micropores and interconnected micro-mesoporous structure. As an expectation, the optimized HPCs offers a promising new support for the high selective capture of carbon dioxide in the future.
Keywords: activation; carbon dioxide adsorption; hierarchical porous carbons; micro-mesoporous structure; template method.
Copyright © 2020 Zhang, Wang, Luo, Lu, Peng, Wang and Han.