A Tris(bipyridine)ruthenium(II)-β-Cyclodextrin Derivative: Synthesis, Luminescent Properties, and Application in Electrochemiluminescence DNA Sensors

Hong Chen; Xiuhua Wang; Yantao Qi; Shanshan Zheng; Qiong Chen; Pingang He; Fan Zhang; Fan Yang; Jie Tang; Yuzhi Fang

doi:10.1002/cplu.201300071

A Tris(bipyridine)ruthenium(II)-β-Cyclodextrin Derivative: Synthesis, Luminescent Properties, and Application in Electrochemiluminescence DNA Sensors

Chempluschem. 2013 Aug;78(8):780-784. doi: 10.1002/cplu.201300071. Epub 2013 Jun 11.

Authors

Hong Chen¹, Xiuhua Wang¹, Yantao Qi², Shanshan Zheng¹, Qiong Chen¹, Pingang He¹, Fan Zhang¹, Fan Yang¹, Jie Tang², Yuzhi Fang¹

Affiliations

¹ Department of Chemistry, State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241 (P. R. China).
² Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, East China Normal University, Shanghai 200062 (P. R. China).

PMID: 31986682
DOI: 10.1002/cplu.201300071

Abstract

Miraculous metallocyclodextrin: A new polynuclear metallocyclodextrin complex, tris(bpyRu)-β-CD (bpy=bipyridine), was successfully synthesized. This complex possesses molecular-recognition functions and unique luminescent properties. A tris(bpyRu)-β-CD film was fabricated and utilized in a electrochemiluminescence (ECL) DNA sensor based on its molecular-recognition and luminescence characteristics.

Keywords: cyclodextrins; host-guest systems; luminescence; ruthenium; sensors.

Abstract

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