Insights into compositional changes of dissolved organic matter during a full-scale vermicomposting of cow dung by combined spectroscopic and electrochemical techniques

Abstract

Various spectroscopic and electrochemical techniques combined was used to investigate the compositional changes of dissolved organic matter (DOM) and the difference in humification degree during full-scale cow dung vermicomposting. This study also investigated that whether the two techniques could be used as humification indices. The physicochemical characteristics of vermicompost were superior to those of the control, indicating that vermicomposting significantly accelerated the humification process, which was confirmed by spectroscopic and electrochemical analyses. Meanwhile, the changes of three components identified and electron transfer capacities in vermicomposting further revealed that vermicomposting resulted in significant compositional changes of DOM and higher humification degree. Partial least squares path modeling and redundancy analysis revealed that the two techniques could be used as humification indices for vermicomposting. These results of this study demonstrated that the combination of spectroscopy and electrochemistry was applicable to characterize the compositional changes of DOM and the humification degree of vermicomposting.

Keywords: Cyclic voltammograms; Dissolved organic matter; Electron accepting capacity; Excitation-emission matrix-parallel factor analysis; Vermicomposting process.