Is It Possible To Prepare a Heterometal Anderson-Evans Type Anion?

Anna A Mukhacheva; Victoria V Volchek; Vadim V Yanshole; Nikolay B Kompankov; Artem L Gushchin; Enrico Benassi; Pavel A Abramov; Maxim N Sokolov

doi:10.1021/acs.inorgchem.9b02898

Is It Possible To Prepare a Heterometal Anderson-Evans Type Anion?

Inorg Chem. 2020 Feb 17;59(4):2116-2120. doi: 10.1021/acs.inorgchem.9b02898. Epub 2020 Jan 24.

Authors

Anna A Mukhacheva^{1

2}, Victoria V Volchek¹, Vadim V Yanshole^{2

3}, Nikolay B Kompankov¹, Artem L Gushchin^{1

2}, Enrico Benassi^{2

4}, Pavel A Abramov^{1

2

5}, Maxim N Sokolov^{1

2}

Affiliations

¹ Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Akad. Lavrentiev Avenue , 630090 Novosibirsk , Russia.
² Novosibirsk State University , 2 Pirogova Avenue , 630090 Novosibirsk , Russia.
³ International Tomography Center , Institutskaya str. 3a , 630090 Novosibirsk , Russia.
⁴ Shihezi University , 280 North 4th Road , Shihezi , Xinjiang 832000 , PR China.
⁵ South Ural State University , 76 Lenin Avenue , Chelyabinsk , Russia 454080.

PMID: 31976666
DOI: 10.1021/acs.inorgchem.9b02898

Abstract

Reaction of [SbW₉O₃₃]^9- with [Pt(H₂O)₂(OH)₄] results in the first example of the mixed addenda Anderson-Evans type Pt^IV{Sb^V(OH)₂}W^VI₅O₂₂]^7- anion, isolated and characterized as K₆Na₂[Pt{Sb(OH)₂}W₅O₂₂](NO₃)_0.1(OH)_0.9̇11H₂O (1).