The removal of phosphate by thermally treated red mud from water: The effect of surface chemistry on phosphate immobilization

Abstract

This study investigated thermal treatment of red mud (RM) and its effect on phase composition, surface property, and sorption capacity exemplified by phosphate. Dehydration (∼600 °C), decomposition of carbonate minerals (700 °C-800 °C), and silicate/aluminate formation (900 °C-1000 °C) occurred upon thermal treatment of RM. Grain growth and vitrification that rendered initial morphology changes and decreased the specific surface area of RM from 26.5 to 4.1 m²/g when treated from 600 to 1000 °C, respectively. Surface acidity, i.e., intrinsic acidity constant and surface acidity density, decreased as well after thermal treatment at 600 °C due to burnouts of organics then increased upon further elevated-temperature treatment because of phase transformation. Thermal activation enhanced phosphate adsorption density (μmol/m²). Multilayer sorption aided by leached metal ions was responsible for phosphate immobilization.

Keywords: Bauxite residue; Electric double layer; Sorption; Surface acidity; Surface precipitation.