Highly efficient decomposition of toluene using a high-temperature plasma-catalysis reactor

Abstract

Plasma-catalysis technologies (PCTs) have the potential to control the emissions of volatile organic compounds, although their low-energy efficiency is a bottleneck for their practical applications. A plasma-catalyst reactor filled with a CeO₂/γ-Al₂O₃ catalyst was developed to decompose toluene with a high-energy efficiency enhanced by the elevating reaction temperature. When the reaction temperature was raised from 50 °C to 250 °C, toluene conversion dramatically increased from 45.3% to 95.5% and the energy efficiency increased from 53.5 g/kWh to 113.0 g/kWh. Conversely, the toluene conversion using a thermal catalysis technology (TCT) exhibited a maximum of 16.7%. The activation energy of toluene decomposition using PCTs is 14.0 kJ/mol, which is far lower than those of toluene decomposition using TCTs, which implies that toluene decomposition using PCT differs from that using TCT. The experimental results revealed that the Ce³⁺/Ce⁴⁺ ratio decreased and O_ads/O_latt ratio increased after the 40-h evaluation experiment, suggesting that CeO₂ promoted the formation of the reactive oxygen species that is beneficial for toluene decomposition.

Keywords: Activation energy; CeO(2)/γ-Al(2)O(3); Energy efficiency; High temperature; Plasma catalysis; Toluene.