The selective separation of ions in terms of extremely similar size and properties remains an important challenge in water purification. We innovated a kind of porous nanofilm via interfacial polymerization using rigid heterocyclic ligands to achieve high valent cation selectivity and rapid water/ion transport. The interconnected microporosity and uniformly distributed cation-affinitive sites of the ultrathin membranes enabled water permeation (7.5 L m-2 h-1 bar-1), ion permeance of Na+ (1.5 mol m-2 h-1 bar-1), and Mg2+/Na+ permselectivity (2.1) during nanofiltration. The forward osmosis exhibited a prominent water flux of 95 LMH at 1 M NaCl draw solution, which expanded various applications. The polyarylate membranes comprising 4,7-diphenyl-1,10-phenanthroline showed a higher water permeation and ion selectivity than the planar monomers, e.g., resorcinol. A distinct fluorescence responsiveness existed between membranes and cations for the interaction characterization. Host-guest nuclear magnetic resonance (NMR) spectroscopy and solid-state nuclear magnetic resonance spectroscopy characterized the preferential affinitive of divalent/high-valent cations in the interconnected microporous powders; an ultraviolet spectrophotometer characterized the light responsiveness of the porous nanofilms. Such an active membrane has potential applications in selective separation and adsorption of cations, photocatalytic materials, photosensors, and other fields.
Keywords: ion permeance; nanofiltration; permselectivity; porous nanofilm; water permeation.