High Energy Density Materials Incorporating 4,5-Bis(dinitromethyl)-Furoxanate and 4,5-Bis(dinitromethyl)-3-Oxy-Furoxanate

Lianjie Zhai; Xiaoni Qu; Bozhou Wang; Fuqiang Bi; Sanping Chen; Xuezhong Fan; Gang Xie; Qing Wei; Shengli Gao

doi:10.1002/cplu.201600287

High Energy Density Materials Incorporating 4,5-Bis(dinitromethyl)-Furoxanate and 4,5-Bis(dinitromethyl)-3-Oxy-Furoxanate

Chempluschem. 2016 Nov;81(11):1156-1159. doi: 10.1002/cplu.201600287. Epub 2016 Jul 29.

Authors

Lianjie Zhai¹, Xiaoni Qu², Bozhou Wang¹, Fuqiang Bi¹, Sanping Chen², Xuezhong Fan¹, Gang Xie¹, Qing Wei¹, Shengli Gao¹

Affiliations

¹ State Key Laboratory of Fluorine and Nitrogen Chemicals, Xi'an Modern Chemistry Research Institute, Xi'an, 710065, China.
² Key Laboratory of Synthetic and, Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi, 710069, China.

PMID: 31964093
DOI: 10.1002/cplu.201600287

Abstract

3-Oxy-furoxanate is immobilized in a heterometallic energetic metal-organic framework (MOFs). Two furoxan-based MOFs ([Ag₂ K₄ (BDOFO)(BDFO)₂ (H₂ O)₆ ]_n , [K₂ (BDFO)]_n ) and a salt ([(BDFO^2- )(NH₂ NH₃ ⁺ )₂ (H₂ O)]_n (BDOFO^2- =4,5-bis(dinitromethyl)-3-oxy-furoxanate, BDFO^2- =4,5-bis(dinitromethyl)-furoxanate) are synthesized and their energetic performance evaluated. This study outlines the systematic investigation of detonation performance of 3-oxy-furoxan and its derivatives.

Keywords: energetic materials; furoxanates; metal-organic frameworks; oxygen balance.

Abstract

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