Relationship between polyphenolic content, antioxidant properties and oxygen consumption rate of different tannins in a model wine solution

Abstract

The polyphenolic content and the antioxidant capacity of seven tannins with different botanical origin were measured with spectrophotometric methods (Folin-Ciocalteu, Total Polyphenols Index, DPPH, FRAP), HPLC (phloroglucinolysis), voltammetric analysis (Linear Sweep Voltammetry, LSV). The oxygen consumption rate (OCR) was measured in an oxygen saturated model wine solution, containing transition metals and metabisulphite, with a noninvasive luminescence-based technology. The results showed a high variability in polyphenolic concentration related to the botanical origin of tannins. The OCR determined over 21 days was described by quadratic equations, with coefficients varying with tannin botanical origin, dose and SO₂ concentration. The tannins ranked differently for antioxidant capacity, depending on the kind of test. The oxygen consumption parameters were positively correlated only with the LSV data measured with anodic current between 100 and 1200 mV (LSV_1200mV) and with the FRAP index.

Keywords: Antioxidant activity; Linear sweep voltammetry; Oxygen consumption rate; Tannins.