In order to study the effect of interfacial wettability of separator on electrochemical properties for lithium-ion batteries, two different kinds of polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) solution are prepared and used to coat onto a polypropylene (PP) microporous membrane. It is found that the cell performance of a coated separator using aqueous slurry (WPS) is better than that of the coated separator using acetone (APS) as the solvent. The separator with flat and pyknotic surface (PP and APS) has a strong polar action with the electrolyte, where the polar part is more than 80%. To the contrary, the WPS has a roughness surface and when the PVDF-HFP particles accumulate loose, it makes the apolar part plays a dominate role in surface free energy; the dispersive energy reaches to 40.17 mJ m-2. The WPS has the lowest immersion free energy, 31.9 mJ m-2 with the electrolyte, and this will accelerate electrolyte infiltration to the separator. The loose particle accumulation also increases the electrolyte weight uptake and interfacial wettability velocity, which plays a crucial role in improving the cell performance such as the ionic conductivity, discharge capacity and the C-rate capability.
Keywords: Li–ion battery; coated separator; immersion free energy; interfacial wettability.