Photoplethysmography (PPG) provides a simple, convenient and noninvasive method to assess pulse oximetry. Several attempts have been made to use PPG also to estimate blood pressure and arterial stiffness. This paper attempts to assess obesity classes, age group, and hypertension classes using PPG measured from the finger. One set of features was derived from the normalized pulse width of PPG and the other from original PPG. The features were calculated based on the pulse decomposition analysis using five lognormal functions and the up-slope of the PPG pulse. Using kNN and SVM as classifiers, the results were validated using leave-one-out validation. Performances of both features sets have no significant difference, and the kNN outperformed the SVM. The best accuracies are 93%, 88%, and 92% for obesity (5 classes), age group (7 classes), and hypertension (4 classes) respectively. These three assessment targets have a strong relationship with arterial stiffness, therefore it also leads to a study about arterial stiffness using PPG. Width normalization to 1 second might affect some features points based on pulse decomposition analysis. This study also found that the up-slope analysis might give good indices when width normalization was employed. However, these findings still require more experiments to gain conclusions that are more comprehensive.