Effects of flushing flows on the transport of mercury-polluted particulate matter from the Flix Reservoir to the Ebro Estuary

Abstract

Polluted sediments retained in water reservoirs are potential sources of deleterious materials downstream, especially during floods or flushing flows (FFs). Their interaction with these events is important for determining potential risks and evaluating management actions. In the Ebro River, the Flix Reservoir accumulated a deposit of more than 3 × 10⁵ t of industrial waste with high Hg concentrations. Because suspended particulate matter (SPM) is the main driver of Hg pollution downriver, this study analyses the transport of particulate matter and Hg pollution from the Flix Reservoir to the Ebro Estuary during FFs. Time series of currents, turbidity and downward particulate matter fluxes were obtained by current meters, turbidimeters and sediment traps assembled in benthic tripods. They were deployed in the reservoir and at two locations in the estuary during two recording periods that each captured a flushing flow (FF) event. In addition, SPM samples were collected during the study period at several locations along the river course, from upstream of the Flix Reservoir down to the river mouth, to measure the suspended particulate matter and associated Hg mobilized downstream. A continuous background level of Hg pollution was observed during the deployment periods, but the Hg and particulate matter fluxes increased by between one and two orders of magnitude during FFs. Though the two events reached similar water discharges, the first FF was after the wet season and generated lower particulate matter concentrations and fluxes, but higher Hg contents than the second, which occurred after the dry season. The higher available particulate matter in the second event diluted the polluted Hg particle load more than the first event. Thus, similar FFs may result in different Hg concentration and sediment transport episodes, largely depending on the previous hydrological regime and the river sediment availability. These findings should be considered for FF management.

Keywords: Ebro river; Flushing flow; Mercury transport; Particulate matter; Polluted reservoir; Salt wedge estuary.