Irrigation implementation promotes increases in salinity and nitrate concentration in the lower reaches of the Cidacos River (Navarre, Spain)

D Merchán; L Sanz; A Alfaro; I Pérez; M Goñi; F Solsona; I Hernández-García; C Pérez; J Casalí

doi:10.1016/j.scitotenv.2019.135701

Irrigation implementation promotes increases in salinity and nitrate concentration in the lower reaches of the Cidacos River (Navarre, Spain)

Sci Total Environ. 2020 Mar 1:706:135701. doi: 10.1016/j.scitotenv.2019.135701. Epub 2019 Nov 23.

Authors

D Merchán¹, L Sanz², A Alfaro³, I Pérez², M Goñi⁴, F Solsona⁵, I Hernández-García⁴, C Pérez⁵, J Casalí⁴

Affiliations

¹ Public University of Navarre, Campus de Arrosadía, 31006 Pamplona, Navarra, Spain. Electronic address: d.merchan@unavarra.es.
² Environmental Management of Navarre, C/ Padre Adoain, 219 Bajo, 31015 Pamplona, Navarra, Spain.
³ Navarre Institute of Agricultural and Food Technologies and Infrastructures, Avda. Serapio Huici 22, 31610 Villava, Navarra, Spain.
⁴ Public University of Navarre, Campus de Arrosadía, 31006 Pamplona, Navarra, Spain.
⁵ Department of Rural Development, Environment and Local Administration, Government of Navarre, C/ González Tablas 9, 31003 Pamplona, Navarra, Spain.

PMID: 31940725
DOI: 10.1016/j.scitotenv.2019.135701

Abstract

The shift from rainfed to irrigated agriculture is associated with a change in the fertilization rates due to increases in expected production and the fact of growing more N demanding crops. In addition, the circulation of irrigation return flows (IRF) mobilizes soluble salts stored in soils or geological materials. As a consequence, it implies severe modifications in the dynamics and total amount of soluble salts and nitrogen exported, especially in semi-arid watersheds. In this study, long-term data collected by the regional authorities was used to assess the effects of irrigation implementation on salinity (using electrical conductivity, EC, as a proxy) and nitrate concentration (NO₃^-) after the transformation of ca. 77 km² from rainfed to irrigated agriculture in the Cidacos River (CR) watershed. The results indicate that water quality in the lower reaches of the CR was significantly modified after the diffuse incorporation of IRF. In contrast, neither EC nor NO₃^- were different in those monitoring stations whose contributing watersheds did not include transformed area. In addition, the temporal dynamics in the analysed variables shifted from a rainfed land signal typical in the region to an irrigated land signal, and the hydrochemical type of the CR shifted from mixed-to-Na⁺-mixed-to-HCO₃^- to mostly Na⁺-mixed type, typical of waters affected by IRF in the region. Groundwater EC and NO₃^- also increased in those wells located within the irrigated area. Although there are great uncertainties in the actual amount of salt and N reaching the CR via IRF, the expected contribution of waste water spilled into the CR is minor in comparison to other sources, mostly agricultural sources in the case of N. The observed changes have promoted the designation of the lower reaches of the CR as "affected" by NO₃^- pollution, and the whole CR watershed as a Nitrate Vulnerable Zone, with the emergent question about whether irrigation implementation as carried out currently in Spain is against the environmental objectives of the Water Framework Directive.

Keywords: Irrigation return flows; Land use change; Nitrate pollution; Salinization of water bodies; Water quality.