The changes in some potentially toxic elements (PTEs) including lead (Pb), cadmium (Cd), arsenic (As), iron (Fe), zinc (Zn), and copper (Cu) during pekmez (grape molasses-like syrup) processing and the utilization of various types of clarifiers (white soil, bentonite, and gelatin) in two levels (1.5 and 3% w/w) were analyzed. The average concentrations of Pb, Cd, As, Fe, Zn, and Cu in grape samples were measured as 0.055 ± 0.005, 0.030 ± 0.002, 0.044 ± 0.002, 2.882 ± 0.013, 2.372 ± 0.088, and 1.194 ± 0.01 μg g-1. During pekmez production, the range of changes in Pb, Cd, As, Fe, Zn, and Cu was -43.38% to 40.25%, -55.49% to 0.23%, -76.15% to 1.80%, -74.15% to 58.47%, -40.55% to -18.12%, and -83.16% to -21.39%, respectively. The effect of the clarification process on the PTEs depended on the type and concentration of both PTE and clarifier agent used while the incorporation of gelatin resulted in a significant reduction in all of PT. Graphical abstract.
Keywords: Contamination; Fate; Grape; PTEs; Pekmez; Unit operation.