Hydrotropic pretreatment on distillery stillage for efficient cellulosic ethanol production

Abstract

Effectiveness of hydrotropic delignification using sodium cumene sulfonate for pretreatment of rye, wheat and maize stillage for further use in the production of bioethanol was evaluated. The highest stillage biomass extractives was obtained for a biomass particle size <1.0 mm, when exposed to 131 °C for 1 h at 20% v/v hydrotrope concentration. It has been shown that hydrotropic treatment causes changes in the stillage biomass structure (increase in porosity) and reduces the lignin content in biomass by 7-17%. Delignification with a hydrotrope also increased the concentration of fermentable sugars in the media prepared with stillage biomass, which led to a higher final ethanol concentration (up to ca. 3.5 g/L). Hydrotropic treatment is an effective way of pretreatment of stillage biomass. It provides a high degree of biomass bioconversion and creates the prospect of integrating the 1st and 2nd generation ethanol production process to more fully utilize the raw material.

Keywords: Cellulosic ethanol; Distillery stillage; Hydrotrope pretreatment; NaCS.